Which of the following carbohydrates is formed when aqueous decomposition of starch is done?

  1. Sucrose
  2. Glucose
  3. Glucose and Fructose
  4. Fructose

Answer (Detailed Solution Below)

Option 2 : Glucose
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Detailed Solution

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The correct answer is Glucose.

Key Points

Concept:

  • Starch is a polysaccharide that occurs in plants in the form of granules which are found mainly in seeds, fruits, tubers, and roots of plants.
  • It is a mixture of two polysaccharides amylose 20% and amylopectin 80%.
  • Amylose is water-soluble while amylopectin is insoluble.
  • Both amylose and amylopectin are polymers of glucose.
  • Amylose is composed of 60 -300 glucose units linked together to form unbranched chains.
  • On the other hand, amylopectin is a branched-chain polysaccharide made up of about 1000 glucose units.
  • The structures of amylose and amylopectin are given which are composed of glucose units

F1 Puja J Anil 18.03.21 D1

Explanation:
Hydrolysis of starch:

  • On hydrolysis with hot dilute acids, starch yields a syrupy mixture of glucose maltose and high molecular weight saccharides.
  • It changes to dextrin at temperatures between 200 - 250 0C.
  • The digestive enzymes in humans convert starch ultimately to glucose which is the source of energy.
  • The reaction scheme is:

 

F1 Puja J Anil 18.03.21 D2

Hence, Glucose is formed when the aqueous decomposition of starch is done.
Additional Information

  • Starch is a white amorphous solid having no definite melting point. It has no taste or smell.
  • It is insoluble in water.
  • Starch gives a blue colour with a drop of iodine solution.
  • Starch doesn't reduce Tollen's or Fehling's solution.
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