Which among the following methods is used to separate the constituents present in compound?

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CDS General Knowledge 3 Sep 2023 Official Paper
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  1. Electrochemical method
  2. Heating method
  3. Fractional distillation
  4. Decomposition followed by ion exchange

Answer (Detailed Solution Below)

Option 1 : Electrochemical method
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Detailed Solution

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The correct answer is Electrochemical method.

Key Points

  • The electrochemical method is used to separate elements in a compound through processes like electrolysis, where electrical energy is used to drive a non-spontaneous reaction.
  • During electrolysis, compounds such as water (H₂O) or sodium chloride (NaCl) are broken down into their constituent elements, like hydrogen and oxygen, or sodium and chlorine.
  • This method is widely applied in industries such as metal extraction (e.g., aluminum from bauxite using Hall-Héroult process).
  • Electrochemical separation is a clean and efficient way to isolate elements from ionic compounds, especially when thermal decomposition is not feasible.
  • It relies on the movement of ions in an electrolytic solution and requires an external power source to initiate the reaction.

Additional Information

  • Electrolysis
    • A technique where electric current is passed through a substance to effect a chemical change.
    • Used in the purification of metals and the production of chemical compounds like chlorine gas and sodium hydroxide.
  • Ionic Compounds
    • Compounds composed of ions held together by electrostatic forces called ionic bonding.
    • These are the typical targets for electrochemical decomposition due to their charged nature.
  • Electrodes
    • Two conductors used in electrolysis: anode (positive) and cathode (negative).
    • Different reactions occur at each electrode, leading to the separation of elements.
  • Applications in Industry
    • Used in extraction of reactive metals like aluminum, electroplating, and water treatment plants.
    • Also employed in hydrogen production as part of renewable energy systems.
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