If the radius of an in a close-packed hexagonal crystal is r, the length of the edge of the unit cell a is:

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  1. r/2
  2. r/4
  3. 2r
  4. 2r/3

Answer (Detailed Solution Below)

Option 3 : 2r
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Explanation:

Hexagonal Close-Packed (HCP) Crystal Structure

Definition: The hexagonal close-packed (HCP) crystal structure is one of the most efficient ways of arranging spheres in a solid, allowing atoms to pack together as closely as possible. In this structure, each atom has 12 nearest neighbors, and the atoms are packed in such a way that the distances between them are minimized.

 

Characteristics of various types of structures are shown in the table below:

Characteristics

BCC

FCC

HCP

a to r relation

\(a = \frac{{4r}}{{√ 3 }}\)

\(a = 2√ 2 r\)

\(a = 2r\)

The average number of atoms

2

4

6

Coordination number

8

12

12

APF

0.68

0.74

0.74

Examples

Na K V Mo Ta W

Ca Ni Cu Ag Pt Au Pb Al

Be Mg Zn Cd Te

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