The major products A and B formed in the following reactions are
F3 Vinanti Teaching 29.05.23 D64

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CSIR-UGC (NET) Chemical Science: Held on (15 Dec 2019)
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  1. F3 Vinanti Teaching 29.05.23 D65
  2. F3 Vinanti Teaching 29.05.23 D66
  3. F3 Vinanti Teaching 29.05.23 D67
  4. F3 Vinanti Teaching 29.05.23 D68

Answer (Detailed Solution Below)

Option 1 : F3 Vinanti Teaching 29.05.23 D65
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Seating Arrangement
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Detailed Solution

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Concept:

Reactivity difference of the both the reagents will lead to formation of different products.

F3 Vinanti Teaching 29.05.23 D69Reagent I is having terminal epoxide ring with secondary alkyl chloride group. Chlorine is poor leaving group than bromine and moreover it is present on secondary position, thus it can not attack directly.

Reagent II is having halide group i.e., Bromine on terminal position and is good leaving group both of these point making it more reactive reagent than I.

Role of HgCl2 is depotection of Dithiane ring by SN2 mechanism.

Mechanism:

→ Reaction with reagent I:
F3 Vinanti Teaching 29.05.23 D70

→ Reaction with reagent II:
F3 Vinanti Teaching 29.05.23 D71

Conclusion:-

So, The major products A and B formed in the following reactions are option 1

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