Question
Download Solution PDFIn the ccp packing, the number of lattice points per unit area in the planes is in the order
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CSIR-UGC (NET) Chemical Science: Held on (26 Nov 2020)
Answer (Detailed Solution Below)
Option 3 : (111) > (100) > (110)
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Download Solution PDFConcept:
Cubic Close Paking:
- The cubic close packing (ccp) is the name given to a crystal structure. When we put atoms in the octahedral void, the packing is the of the form ABCABC, the packing is known as cubic close packing (ccp).
Explanation:
- In case of (100) plane, 5 lattice points are present in the area is a2. Thus, the area occupied by 1 lattice point is (a2/4)=0.20a2.
- In case of (110) plane, 6 lattice points are present in the area is \(\sqrt 2 {a^2}\) Thus, the area occupied by 1 lattice point is \({{\sqrt 2 {a^2}} \over 6}\)=0.23a2.
- In case of (111) plane, 6 lattice points are present in the area \({{\sqrt 3 } \over 4} \times \sqrt 2 a \times \sqrt 2 a = {{\sqrt 3 } \over 2}{a^2}\). Thus, the area occupied by 1 lattice point is \({{\sqrt 3 } \over {12}}{a^2}\) = 0.14a2.
- Thus, In the ccp packing, the number of lattice points per unit area in the planes is in the order (111) > (100) > (110).
Conclusion:-
So, In the ccp packing, the number of lattice points per unit area in the planes is in the order (111) > (100) > (110)
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