Which of the following best represents the relationship between internal energy 'U' of an ideal gas and its absolute temperature 'T'?

Answer (Detailed Solution Below)

Option 2 :
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The correct answer is option 2) 

CONCEPT:

  • Ideal gas: An ideal gas is a hypothetical concept where it is assumed that:
    • There are no intermolecular forces of attraction between the molecules of the gas.
    • The volume occupied by the gas molecules is negligible.
  • The kinetic energy of ideal gas:
    • The kinetic energy of the gas comes from the temperature of the gas. Greater the temperature, the more the kinetic energy.

The average kinetic energy per molecule of a gas is given by:

​Where T is the temperature of the gas IN Kelvin and kB is the Boltzmann's constant (1.38 × 10-23 J/K)

EXPLANATION:

  • There are no attractive forces between the gas molecules of an ideal gas. Hence, the internal energy of the gas will only be kinetic energy i.e. U = KE.

The kinetic energy of an ideal gas is dependent on its temperature as:

⇒ KE ∝ T

⇒  U ∝ T

Therefore, the plot of internal energy vs time will be a straight line through the origin as shown in option 2).

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