Question
Download Solution PDFThe hydrolysis constant for the salts of weak base and strong acid is given by:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
Hydrolysis Constant for Salts of Weak Base and Strong Acid
- Hydrolysis occurs when salts of weak bases and strong acids dissociate in water, producing ions that react with water to affect the pH.
- The hydrolysis constant (Kh) is the equilibrium constant for this reaction and depends on the dissociation constants of the base and acid.
- The relationship between Kh, Kw, Ka, and Kb is derived from the properties of the weak base and the strong acid.
EXPLANATION:
- For salts derived from a weak base and a strong acid:
- The cation from the weak base undergoes hydrolysis, producing H+ ions.
- Hydrolysis constant (Kh) is defined as:
Kh = Kw / Kb
Where:
- Kw is the ionic product of water.
- Kb is the dissociation constant of the weak base.
Therefore, the correct answer is Kw / Kb.
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