The equilibrium constant for a reaction is not affected by the presence of: 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. Lemperature 
  2. Pressure 
  3. Catalyst 
  4. PH = 4

Answer (Detailed Solution Below)

Option 3 : Catalyst 
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DSSSB PGT Hindi Full Test 1
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Detailed Solution

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CONCEPT:

Equilibrium Constant and Its Dependence

  • The equilibrium constant (K) is a measure of the extent of a reaction at equilibrium at a given temperature.
  • The equilibrium constant depends on the temperature of the system because it is derived from the Gibbs free energy change (ΔG).
  • The relationship between the equilibrium constant and temperature is given by the van 't Hoff equation.
  • Other factors, such as pressure, pH, or the presence of a catalyst, do not affect the value of the equilibrium constant directly because K is only a function of temperature.

EXPLANATION:

  • A catalyst speeds up the rate of both the forward and reverse reactions equally, without altering the equilibrium concentrations of reactants and products.
  • Since the equilibrium constant (K) depends only on the ratio of the concentrations of the products and reactants at equilibrium, the catalyst has no effect on its value.
  • Pressure and pH may shift the position of equilibrium (Le Chatelier's Principle), but they do not change the value of K itself.
  • Temperature, on the other hand, can change the equilibrium constant because it affects the Gibbs free energy (ΔG).

Therefore, the equilibrium constant for a reaction is not affected by the presence of a catalyst.

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