Question
Download Solution PDFIn which year did Langmuir reform the Lewis concept by abandoning the idea of a stable cubical arrangement of the octet and introducing the term ‘covalent bond’?
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFThe correct answer is 1919.
Key Points
- Langmuir in 1919 refined the Lewis postulation by abandoning the idea of the stationary cubical arrangement of the octet, and by introducing the team covalent bond.
- Covalent bonds;-
- They are formed by the sharing of electrons between two atoms so that both can achieve a filled outermost shell.
- When two atoms share one electron pair they are said to be joined by a single covalent bond.
- In many compounds, we have multiple bonds between atoms. The formation of multiple bonds envisages the sharing of more than one electron pair between two atoms.
- If two atoms share two pairs of electrons, the covalent bond between them is called a double bond.
- When combining atoms share three electrons Paris as in the case of two nitrogen atoms in the N2 molecule and the two carbon atoms in the ethyne molecule, a triple bond is formed.
Additional Information
- The first description of covalent bonding was provided by Gilbert N. Lewis in terms of the sharing of electron pairs between atoms
- He related the process to the attainment of noble gas configurations by reacting atoms as a result of sharing of electrons.
- Kossel and Lewis in 1916 developed a theory of chemical combination between atoms known as the electronic theory of chemical bonding.
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